Frenkel Excitons in Ordered PbI2Clusters Incorporated into Zeolite
作者:
ZiKang Tang,
Yasuo Nozue,
Osamu Terasaki,
Takenari Goto,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 218,
issue 1
页码: 61-66
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208047016
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Diffuse reflection spectra are measured for (PbI2)5clusters incorporated into supercages of zeolite LTA crystals, where the Frenkel exciton of cluster crystal is expected to be realized. The reflectivity at the exciton resonance energy drastically increases as the loading density nears the saturation level. This result can not be interpreted by the increase of the cluster density, but by the cluster ordering. We propose the order-induced decrease in the damping energy of the Frenkel exciton, because the motional narrowing of the exciton is expected in the ordered (PbI2)5clusters. Electron diffraction pattern shows that clusters are arrayed in twice period of the zeolite cages.
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