Influence of temperature on mesophase textures of ethyl-acetyl cellulose/dichloroacetic acid solution
作者:
Huang Yong,
Zhou Jianye,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1990)
卷期:
Volume 29,
issue 2-3
页码: 117-128
ISSN:0022-2348
年代: 1990
DOI:10.1080/00222349008245768
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The variation of mesophase textures of ethyl-acetyl celluose/ dichloroacetic acid solution with temperature was studied by polarizing microscopy and small-angle light scattering. It was found that the degree of order of polymer chains was different in different mesophase zones. When the solution was heated at a speed larger than 5 K/min, the mesophase with a relatively low degree of order could first transform into the isotropic phase. If the solution was heated slowly enough, however, the mesophase aggregates could become smaller, but the degree of order of polymer chains in the mesophase did not decrease with increasing temperature. When the solution transformed from the isotropic state to the anisotropic one, ordered domains were first formed, and then the disk-like texture appeared.
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