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An experimental and theoretical study of the thermal stability of the nitropyridines

 

作者: G.P.Sharnin,   V.V.Zverev,   I.Sh.Saifullin,   I.S.Gaisin,   I.F.Falyakhov,   V.V.Dubikhin,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  （Springer Available online 2004）
卷期: Volume 30, issue 3  

页码: 368-371

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00949576

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.A study of the kinetics of gas-phase nitropyridine breakdown has led to the development of equations relating the kinetic decomposition parameters and the energy parameters of the molecule.2.2-Nitro-, 2-amino-5-nitro-, 4-nitro-, and 3,5-dinitropyridines decompose through C-NO2bond rupture. The energy required for bond rupture has been determined.

 

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