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Catalytic behavior of a silica‐supported polystannazane‐copper complex for the oxidation of methanol to formaldehyde at mild reaction conditions

 

作者: Li‐Ming Tang,   Qiang He,   Mei‐Yu Huang,   Ying‐Yang Jiang,  

 

期刊: Macromolecular Rapid Communications  （WILEY Available online 1995）
卷期: Volume 16, issue 1  

页码: 15-18

 

ISSN:1022-1336

 

年代: 1995

 

DOI:10.1002/marc.1995.030160103

 

出版商: Hüthig&Wepf Verlag

 

数据来源: WILEY

 

摘要:

AbstractA very cheap catalyst, a silica‐supported polystannazane‐copper complex (abbreviated as SiO2SnNCu) was prepared by the reaction of the silica‐supported polystannazane ligand with CuCl2in ethanol. The results showed that SiO2SnNCu can catalyze the oxidation of methanol to formaldehyde in high yield at mild conditions, i.e. at 40°C and 1 atm of oxygen. The catalyst could be recovered and could catalyze the r

 

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