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Deformation mechanism of cellulose gels. IV.General relationship between orientation of the crystalline and that of the amorphous portion

 

作者: P. H. Hermans,   J. J. Hermans,   D. Vermaas,   A. Weidinger,  

 

期刊: Journal of Polymer Science  (WILEY Available online 1948)
卷期: Volume 3, issue 1  

页码: 1-9

 

ISSN:0022-3832

 

年代: 1948

 

DOI:10.1002/pol.1948.120030101

 

出版商: Interscience Publishers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractTen series of model filaments with increasing orientation and swelling degrees ranging between 16 and 1.2 were prepared from three viscoses containing 4, 6, and 10.5% cellulose. Their birefringence was measured and their x‐ray diagrams taken and quantitatively evaluated in order to determine the over‐all orientation of the iiber substance and that of the crystalline portion. It is shown that a general relation exists between the orientation of the crystallites and that of the entire fiber substance which is the same in all fibers stretched in the swollen state. Once the birefringence of a filament is known, the orientation factor of its crystallitee can be computed without taking an x‐ray photograph. From the data further evidence can be derived to the effect that the orientation of the crystallitm cannot be accounted for by the theory of affined deform

 

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