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Glass Transitions in Polymer‐Plasticizer Systems

 

作者: L. Breitman,  

 

期刊: Journal of Applied Physics  (AIP Available online 1955)
卷期: Volume 26, issue 9  

页码: 1092-1098

 

ISSN:0021-8979

 

年代: 1955

 

DOI:10.1063/1.1722157

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Glass temperatures (Tg) of pure and plasticized elastomers have been obtained from dilatometric measurements and from the temperature dependence of angular response to torsional stress. The depression ofTgby a diluent, determined by either method, is a convenient measure of its plasticizing ability. Some compounds which are normally crystalline aboveTgof the pure polymer, but nevertheless compatible with the polymer, depressed the glass temperature. The polymer‐diluent compatibility at low temperatures results either from supercooling, the depression of the melting point of diluent by polymer, or possibly a combination of both phenomena.Tgdecreased as the diluent loading increased to a more or less well defined limit, beyond which further dilution had negligible effect. For diester type plasticizers both &Dgr;Tgmaxand the limiting diluent concentration were linear functions of compatibility, as defined by the extent to which standard polymer vulcanizates were swollen by plasticizer. The viscosities and apparent activation energies for flow (Ev) of hydrocarbon oils correlated with their low temperature plasticizing efficiencies. Pour points and glass temperatures may also be significant properties of the diluents. It is concluded that lowEvand high solvency for polymer are desirable properties for low temperature plasticizers.

 

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