首页   按字顺浏览 期刊浏览 卷期浏览 New probe for high‐temperature nuclear‐magnetic‐resonance spectros...
New probe for high‐temperature nuclear‐magnetic‐resonance spectroscopy with ppm resolution

 

作者: J. F. Stebbins,   E. Schneider,   J. B. Murdoch,   A. Pines,   I. S. E. Carmichael,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1986)
卷期: Volume 57, issue 1  

页码: 39-42

 

ISSN:0034-6748

 

年代: 1986

 

DOI:10.1063/1.1139115

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A new type of instrument has been designed and built to make Fourier transform nuclear‐magnetic‐resonance (NMR) spectroscopic measurements at temperatures to at least 1200 °C, with a resolution of about 1 ppm. A sample is rapidly and repeatedly shuttled between the furnace and the radio frequency (rf) coil of the NMR probe (both located within a high field superconducting magnet), spending most of the time in the furnace. During each cycle, a series of rf pulses may be given and a single free‐induction decay sampled. The rf coil is located outside of the furnace and is maintained at room temperature despite its close proximity to the sample. Electronic stability and coil ‘‘filling factor’’ are thus both optimized. The sample temperature drops below that of the furnace when cycling begins, but rapidly approaches a nearly constant value with only small fluctuations. 99% BN has been successfully used as a sample container in experiments on27Al,29Si, and23Na in molten silicates in the system Na2O–Al2O3–SiO2.

 

点击下载:  PDF (312KB)



返 回