A Novel Stereoselective Route to Alkyl 2-Deoxy-β-D-glucosides via S-(2-Deoxy-α-glucosyl) Phosphorodithioates
作者:
Maria Michalska,
Joanna Borowiecka,
期刊:
Journal of Carbohydrate Chemistry
(Taylor Available online 1983)
卷期:
Volume 2,
issue 1
页码: 99-103
ISSN:0732-8303
年代: 1983
DOI:10.1080/07328308308058811
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Intense interest in sugar components of anthracycline antibiotics and antitumor drugs generated a need for stereoselective methods of synthesis of 2-deoxy sugar glycosides. Although several efficient procedures leading to 2-deoxy-α-glycosides were elaborated, there is no satisfactory general procedure leading to the β-anomers. The methods described are not stereoselective and involve separation of anomeric intermediates of glycosides.
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