RechargeableE’centers in silicon‐implanted SiO2films
作者:
A. Kalnitsky,
J. P. Ellul,
E. H. Poindexter,
P. J. Caplan,
R. A. Lux,
A. R. Boothroyd,
期刊:
Journal of Applied Physics
(AIP Available online 1990)
卷期:
Volume 67,
issue 12
页码: 7359-7367
ISSN:0021-8979
年代: 1990
DOI:10.1063/1.346059
出版商: AIP
数据来源: AIP
摘要:
Implantation of Si in does of 1015–1016cm−2into dry thermal oxides on silicon wafers produces a three‐state MOS memory device. For both positive‐ and negative‐going traps, gate voltage stress up to ±10 MV/cm−1generates stable (±) oxide charge near the gate and (∓) charge near the substrate. Electron paramagnetic resonance (EPR) measurement on corona‐field (≤11 MV/cm) stressed oxides revealsE’centers in regions of positive charge, which may be recycled between the EPR‐visible (+) state and the invisible neutral state. The correspondence of charge and EPR indicates a composite or Feigl‐Fowloer‐YipE’center, O33/4 Si:...+Si 3/4 O3, arising from nonstoichiometric Si fused into the SiO2lattice. Upon trapping an electron, the center rebonds to yield O33/4 SiSi 3/4 O3. The charging parameters of theE’center suggest tunneling of an electron from the (0→+) state, and are consistent with the theoretical prediction of the energy level and Franck–Condon relaxation. The three types ofE’centers observed in this and related studies are compared with theE’&agr;,E&bgr;andE’&ggr;variants of bulk amorphous silica.
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