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Nouvelle Synthese De L'Acide 3-Desoxy-D-Erythro-2-Hexulosonique (KDG) A Partir Du D-Glucose

 

作者: Richard Plantier-Royon,   Daniel Anker,   Janine Robert-Baudouy,  

 

期刊: Journal of Carbohydrate Chemistry  （Taylor Available online 1991）
卷期: Volume 10, issue 2  

页码: 239-249

 

ISSN:0732-8303

 

年代: 1991

 

DOI:10.1080/07328309108543903

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

3-Deoxy-D-erythro-2-hexulosonic acid (KDG), an important metabolite of bacterial polysaccharides degradation was prepared from D-glucose in six stepsviathe synthesis of 2,4-O-isopropylidene-D-erythrose and subsequent Wittig-Horner condensation followed by smooth deprotections of protecting groups. Overall yield was 35% from D-glucose.

 

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