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Uniaxial elongational flow of particle-filled polymer melts

 

作者: J. Greener,   J. R. G. Evans,  

 

期刊: Journal of Rheology  (AIP Available online 1998)
卷期: Volume 42, issue 3  

页码: 697-709

 

ISSN:0148-6055

 

年代: 1998

 

DOI:10.1122/1.550947

 

出版商: The Society of Rheology

 

关键词: Elongational flow;Extensional rheometry;Suspension;Dispersion

 

数据来源: AIP

 

摘要:

Polymer processes which employ elongational flows have been successfully used for shaping ceramics by using crowded (50–60 vol %) suspensions of ceramic particles, but the full realization of their potential rests on an understanding of the extensional flow behavior of filled polymer systems. A uniaxial rheometer was constructed to evaluate the extensional flow properties of crowded suspensions based on polyisobutylene. The shear viscosity was evaluated for comparison using a Weissenberg rheometer and correlated with published literature values for a similar molecular weight polyisobutylene. Trouton’s Law was verified for the unfilled polymer. The shear and elongational viscosities of filled polyisobutylene, containing up to 42 vol % and 45 vol % ceramic, respectively, were measured. The dependence of shear and elongational relative viscosities on powder volume fraction were compared. In uniaxial flow, Trouton’s Law was obeyed for crowded suspensions containing up to 42 vol % ceramic powder.

 

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