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Substituent‐induced chemical shift13C NMR study of substituted 2‐phenylthiazolidines

 

作者: R. Umarani,  

 

期刊: Magnetic Resonance in Chemistry  (WILEY Available online 1992)
卷期: Volume 30, issue 10  

页码: 1027-1029

 

ISSN:0749-1581

 

年代: 1992

 

DOI:10.1002/mrc.1260301020

 

出版商: John Wiley&Sons, Ltd.

 

关键词: 13C NMR;SCS;Substituted 2‐phenylthiazolidines

 

数据来源: WILEY

 

摘要:

AbstractThe analysis of the13C NMR chemical shifts of 16 substituted 2‐phenylthiazolidines shows that the 1,3‐thiazolid‐2‐yl group exerts a deshielding effect at theipsocarbon (C‐1′) and shielding effects at theorthoandparapositions of the benzene ring (C‐2′ and C‐4′), and that the transmission of the resonance effect from the substituents in the phenyl ring to the benzylic carbon (C‐2) in the thiazolidine heterocycle is diminished by the polarizable nitro

 

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