Far IR Spectroscopic Investigations of Nematic Liquid Crystals with Hydrogen Bonded Molecules. Comparison with Nonoriented Systems
作者:
K. Antonova,
M. Petrov,
N. Kirov,
T. Tenev,
H. Ratajczak,
J. Baran,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 261,
issue 1
页码: 63-70
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508033452
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The 6 - 10th homologues of 4-n-alkoxybenzoic acid, i.e. hexyl-, heptyl-, octyl-, nonyl- and decyloxybenzoic acids (60BA, HOBA, OOBA, NOBA and DOBA) are used for the present investigations. Far IR spectroscopy is used to study the state of hydrogen bonding at temperature variation of the nematic liquid crystal phase. The observed spectral bands are assigned to different OH deformation vibrations. From the analysis of the temperature dependence of the spectral band widths a cyclic ↔ open dimer transformation is indicated at different vibration frequencies and polarizations. The activation energy for the dimer and monomer reorientation is calculated and compared with that per hydrogen bond. The correlation lengths parallel and perpendicular to the nematic director (ξ‖ and ξ⊥) are calculated and an anisotropy is found in the temperature dependence of the critical index of the correlation length. A comparison with nonoriented nematics with hydrogen bonded molecules is presented.
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