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Analytical description of theI= 5/2 quadrupole nutation experiment

 

作者: J.A.M. van der Mijden,   R. Janssen,   W.S. Veeman,  

 

期刊: Molecular Physics  (Taylor Available online 1990)
卷期: Volume 69, issue 1  

页码: 53-64

 

ISSN:0026-8976

 

年代: 1990

 

DOI:10.1080/00268979000100041

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The theory of nutation N.M.R. for a quadrupolar nucleus with spin quantumI= 5/2 is presented in an exact, analytical way. It is shown that the nutation spectrum is described by 9 different frequencies each dependent on the orientation of the quadrupole tensor relative to the external field. The frequencies are calculated from the eigenvalues of a 6th-degree secular equation that is reduced to 2 secular equations of order 3. This reduction is obtained by a transformation of bases. An extension of the nutation experiment,xx¯-nutation, is compared with the standard technique. The theoretical spectra are compared with experimental27Al spectra of NH4Al(SO4)2· 12H2O and zeolite NaA.

 

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