Collective Dynamics in Some Phases Consisting of Banana-Shaped Molecules
作者:
Heiko Schmalfuss,
Anton Hauser,
Horst Kresse,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 351,
issue 1
页码: 221-228
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008023271
出版商: Taylor & Francis Group
关键词: Dielectric measurements;banana-shaped molecules;super-structures
数据来源: Taylor
摘要:
Dielectric measurements on two samples of banana-shaped molecules showing a B2and a B7phase were carried out. The low frequency dispersion in the B2phase is interpreted as a collective motion of ferroelectric clusters and the high frequency one as the reorientation of single molecules with a strong positive dipole correlation. In the B7phase a, soft mode-like“ behavior was detected pointing to an additional phase transition. AFM measurements support the existence of helical super-structures which probably appear in B7and in the low temperature phase Bx.
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