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Collective Dynamics in Some Phases Consisting of Banana-Shaped Molecules

 

作者: Heiko Schmalfuss,   Anton Hauser,   Horst Kresse,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 2000)
卷期: Volume 351, issue 1  

页码: 221-228

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008023271

 

出版商: Taylor & Francis Group

 

关键词: Dielectric measurements;banana-shaped molecules;super-structures

 

数据来源: Taylor

 

摘要:

Dielectric measurements on two samples of banana-shaped molecules showing a B2and a B7phase were carried out. The low frequency dispersion in the B2phase is interpreted as a collective motion of ferroelectric clusters and the high frequency one as the reorientation of single molecules with a strong positive dipole correlation. In the B7phase a, soft mode-like“ behavior was detected pointing to an additional phase transition. AFM measurements support the existence of helical super-structures which probably appear in B7and in the low temperature phase Bx.

 

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