Forced Hydrolysis of In(0H)3– arison of Model with Experiments
作者:
Yu Chen,
TerryA. Ring,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 1998)
卷期:
Volume 19,
issue 2-3
页码: 229-247
ISSN:0193-2691
年代: 1998
DOI:10.1080/01932699808913173
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This paper presents a theory that links solution complexation equilibria with a model for precipitation predicting the panicle size distribution. This model uses classical nucleation theory and growth rates by various rate limiting steps for the growth of the crystals. This model is compared to forced hydrolysis experiments where dilute Indium nitrate solutions, acidified with nitric acid, were heated to 80°C. The experiments produced cubic particles of Indium hydroxide. The experiments were monitored for temperature, pH. turbidity, indium concentration in solution and particle size distribution, all as a function of lime for comparison with this model. The model gives an accurate prediction of the evolution of the particle size distribution, pH, turbidity, and indium concentration with time.
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