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Low-frequency dielectric relaxation in columnar hexagonal and micellar inverse cubic mesophases

 

作者: H. KRESSE,   H. SCHMALFUSS,   B. GESTBLOM,   K. BORISCH,   C. TSCHIERSKE,  

 

期刊: Liquid Crystals  (Taylor Available online 1997)
卷期: Volume 23, issue 6  

页码: 891-896

 

ISSN:0267-8292

 

年代: 1997

 

DOI:10.1080/026782997207821

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Dielectric measurements on four diols showing columnar hexagonal and micellar cubic phases were carried out. Besides the known fast local reorientation in theGHz-range, a new absorption in theMHz region was detected. This mechanism was interpreted as a collective motion of the molecules inside the micelles or cylindrical aggregates. The absorption was also found in the isotropic phase. Based upon the interpretation given, the molecular aggregates should also exist in the isotropic state. The electrical conductivity strongly supports the classification as inverse phases.

 

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