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Kinetics of the sulfodeacylation of 2,4,6,2′,6′‐pentamethylbenzophenone, a process comprising successive first‐order reactions occurring by two alternative routes

 

作者: Peter H. Gore,   Esmat F. Saad,   David N. Waters,   Gerald F. Moxon,  

 

期刊: International Journal of Chemical Kinetics  （WILEY Available online 1982）
卷期: Volume 14, issue 1  

页码: 55-62

 

ISSN:0538-8066

 

年代: 1982

 

DOI:10.1002/kin.550140107

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractMesityl 2,6‐xylyl ketone in 89.8% (w/w) sulfuric acid undergoes cleavage to give mesitylenesulfonic acid, xylenesulfonic acid, and carbon dioxide as final products. The reaction has been analyzed in terms of a series of first‐order reactions. Of the two possible reaction paths available it was shown that fission at the mesityl group is responsible for about 98.5% of the overall initial reaction at 2

 

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