Effect of Chlorine Atmosphere on the Anatase‐Rutile Transformation
作者:
Julio Andrade Gamboa,
Daniel M. Pasquevich,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1992)
卷期:
Volume 75,
issue 11
页码: 2934-2938
ISSN:0002-7820
年代: 1992
DOI:10.1111/j.1151-2916.1992.tb04367.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
The anatase‐rutile phase transformation in Ar–Cl2atmosphere has been investigated by X‐ray powder diffraction, thermogravimetry, and scanning electron microscopy. At 950°C the phase transformation in Ar–Cl2atmosphere is about 300 times faster than in air. The growth of crystals of rutile from the vapor phase has been observed. We also determined that anatase powders with adsorbed chlorine rapidly rapidly transformed to rutile and underwent a color change from white to gray when they were heated in Ar at
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