Polarizing Nuclear Spins Via Photo‐Excited Triplet States
作者:
J. Schmidt,
D.J. van den Heuvel,
A. Henstra,
T.‐S. Lin,
W. Th. Wenckebach,
期刊:
Israel Journal of Chemistry
(WILEY Available online 1992)
卷期:
Volume 32,
issue 2‐3
页码: 165-172
ISSN:0021-2148
年代: 1992
DOI:10.1002/ijch.199200023
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractIn this paper we discuss two methods to achieve high nuclear polarizations at room temperature using pulsed EPR techniques and triplet spins which are optically excited by a laser pulse. The results of our experiments, which are performed on a single crystal of napthalene doped with pentacene, show that an unusually high proton spin polarization can be achieved and that the transfer occurs in a time determined by the dipolar interaction between the electron spins of the pentacene guests and the proton spins on the surrounding napthalene molecules.
点击下载:
PDF
(1042KB)
返 回