Nonsteady-State Model for Kinetics of Radical Chain Polymerization. 1. Direct Photoinitiation and Thermal Initiation with Constant Monomer Concentration
作者:
Xiaodong Hu,
Qingsong Hu,
Deyue Yan,
Jing Feng,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1991)
卷期:
Volume 28,
issue 5-6
页码: 503-515
ISSN:0022-233X
年代: 1991
DOI:10.1080/00222339108052103
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Chain radical polymerization with direct photoinitiatlon or thermal initiation and constant monomer concentration has been theoretically studied by dealing precisely with the kinetic differential equations. The expressions for molecular size distribution, number- and weight-average degrees of polymerization, and their dependence on the reaction conditions are derived in analytical form. A computation program allowed easy calculation of these parameters concerned with the resultant polymer.
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