A new model for deformation kinetics of polyethylene terephthalate films
作者:
H.C. Chiu,
S.J. Burns,
M.D. Fiscella,
R.C. Benson,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1994)
卷期:
Volume 33,
issue 1
页码: 87-104
ISSN:0022-2348
年代: 1994
DOI:10.1080/00222349408248081
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Analyzed in this paper are the deformation relationships between temperature; stress, strain; and stress rate in polyethylene terephthalate (PET) near the glass transition temperature. The uniaxial stress rate of inelastic deformation was found to be proportional to the square of the effective stress. A physical model of two simultaneous rate-activated processes with a general activation energy barrier is utilized. We call this “second-order kinetics.” Experimental data obtained by measuring load rate versus load point displacement were analyzed to describe stress relaxation of thin uniaxial strips. The activation enthalpy and activation volume show that the rate-controlling process is second-order.
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