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Conductometric, Viscometric and Ultrasonic Studies of Terbium Laurate in Benzene-Methanol Mixture

 

作者: K.N. Mehrotra,   Neerja Sharma,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1996)
卷期: Volume 31, issue 2  

页码: 127-134

 

ISSN:0031-9104

 

年代: 1996

 

DOI:10.1080/00319109608029565

 

出版商: Taylor & Francis Group

 

关键词: Terbium laurate;viscosity;conductivity;acoustic parameters;CMC

 

数据来源: Taylor

 

摘要:

The conductometric, viscometric and ultrasonic velocity measurements of the solutions of terbium laurate in benzene-methanol mixture (7:3 v/v) were carried out at 40 ± 0.05°C. The conductivity results showed that the soap behaves as a weak electrolyte in dilute solutions. The viscosity results were explained on the basis of equations proposed by Einstein, Vand, Moulik and Jones-Dole and the values of molar volume evaluated by using Einstein's and Vand's equations were in close agreement. The ultrasonic velocity measurements were used to evaluate various acoustic parameters. The results showed that the soap-soap interactions are weaker than soap-solvent interactions in dilute solutions and the soap molecules do not aggregate below the critical micelle concentration in dilute solutions.

 

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