Fit of a nonreptative model of polymer melt dynamics to experimental melt diffusion constant measurements
作者:
Alan T. Yeates,
Jeffrey Skolnick,
Robert Yaris,
期刊:
Journal of Polymer Science Part B: Polymer Physics
(WILEY Available online 1989)
卷期:
Volume 27,
issue 1
页码: 151-154
ISSN:0887-6266
年代: 1989
DOI:10.1002/polb.1989.090270109
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractA model of polymer melt diffusion recently proposed by Skolnick, Yaris, and Kolinski and which does not invoke reptation as the dominant mechanism of polymer melt motion is used to fit polymer self‐diffusion constant data measured by Antonietti, Fölsch, and Sillescu for a homopolymeric melt as well as for a probe in a larger molecular weight matrix. The quality of fit of the data indicates that reptation theory cannot be verified by simple comparison to diffusion constant measuremen
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