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Chelate Extractions Involving Three Liquid Phases: Role of Water

 

作者: DennisR. Gere,   CliftonE. Meloan,  

 

期刊: Separation Science  (Taylor Available online 1968)
卷期: Volume 3, issue 3  

页码: 297-306

 

ISSN:0037-2366

 

年代: 1968

 

DOI:10.1080/01496396808052217

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

An experimental technique has been developed to determine the effect of solvent polarity on the removal of associated water molecules from metal chelates during extraction. It was found that tris(4,7-diphenyl-1,10-phenanthroline)iron(II) perchlorate had two spheres of water associated with it—one that could be displaced by organic solvent and one that could not.

 

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