Investigative Study of Chemical Characterization of Raphia Petiole Lignin by Soda and Kraft Pulping Processes
作者:
ZenatA. Nagieb,
S.O. Odeyemi,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1991)
卷期:
Volume 30,
issue 7
页码: 723-736
ISSN:0360-2559
年代: 1991
DOI:10.1080/03602559108020146
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Soda lignins of raphia petiole have completely different structure from kraft lignins. Soda lignins have higher methoxyl content and fewer phenolic hydroxyl group. From nitro benzene oxidation, soda lignins have a higher percentage of syringaldhyde 18.20 and also a higher S/V molar ratio. This is the reason that soda lignin is composed mainly of syringyl units, while kraft lignin is composed of guaiacyl units. IR spectra show remarkable differences: soda lignins show the strongest bands at 1230–1330 cm−1, attributed to syringyl nucleus; whereas kraft lignins show the strongest bands at 1030 cm−1and 1270 cm−1, which are attributed to the guaiacyl nucleus. NMR spectra were also studied.
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