Solvent Effects in the Graft Copolymerization of Methyl Methacrylate to Polypropylene
作者:
PeterJ. Burchill,
DonM. Pinkerton,
RichardH. Stacewicz,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1980)
卷期:
Volume 14,
issue 1
页码: 79-85
ISSN:0022-233X
年代: 1980
DOI:10.1080/00222338008063210
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Methyl methacrylate can be readily graft copolymerized to polypropylene film by mutual γ-irradiation in vacuo. Graft yields in excess of 1000% can be obtained at low total doses (0.1 Mrad) and dose rates (0.05 Mrad/hr). When the monomer is diluted with solvent mixtures, similar yields can be obtained at lower monomer concentrations due to an accelerative effect. Besides swelling of the polypropylene, the results indicate the importance of solvent on the reaction kinetics of the growing poly(methy1 methacrylate) radicals. A possible explanation of the effect of diluent is presented in terms of polymer chain entanglement.
点击下载:
PDF (260KB)
返 回