首页   按字顺浏览 期刊浏览 卷期浏览 Solvent Effects in the Graft Copolymerization of Methyl Methacrylate to Polypropylene
Solvent Effects in the Graft Copolymerization of Methyl Methacrylate to Polypropylene

 

作者: PeterJ. Burchill,   DonM. Pinkerton,   RichardH. Stacewicz,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1980)
卷期: Volume 14, issue 1  

页码: 79-85

 

ISSN:0022-233X

 

年代: 1980

 

DOI:10.1080/00222338008063210

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Methyl methacrylate can be readily graft copolymerized to polypropylene film by mutual γ-irradiation in vacuo. Graft yields in excess of 1000% can be obtained at low total doses (0.1 Mrad) and dose rates (0.05 Mrad/hr). When the monomer is diluted with solvent mixtures, similar yields can be obtained at lower monomer concentrations due to an accelerative effect. Besides swelling of the polypropylene, the results indicate the importance of solvent on the reaction kinetics of the growing poly(methy1 methacrylate) radicals. A possible explanation of the effect of diluent is presented in terms of polymer chain entanglement.

 

点击下载:  PDF (260KB)



返 回