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E.S.R. study of the conformational kinetics of a biradical

 

作者: E. Alster,   BrianL. Silver,  

 

期刊: Molecular Physics  （Taylor Available online 1986）
卷期: Volume 58, issue 5  

页码: 977-987

 

ISSN:0026-8976

 

年代: 1986

 

DOI:10.1080/00268978600101721

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Intramolecular motion in the biradical N,N'-bis(2,2,6,6-tetramethyl-1-oxyl-4-piperidinyl)ethylenediamine which contains two ionizable amine groups has been studied by E.S.R. spectroscopy. The line-shapes of the spectra as a function of pH and temperature were analysed by density matrix methods to give values for rates and free-energies of activation.

 

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