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Thermoelastic Behavior of Rubber‐Like Materials at Large Deformations

 

作者: Mitchel Shen,  

 

期刊: Journal of Applied Physics  (AIP Available online 1970)
卷期: Volume 41, issue 11  

页码: 4351-4356

 

ISSN:0021-8979

 

年代: 1970

 

DOI:10.1063/1.1658466

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The statistical theory of rubber‐like elasticity requires the energy contribution (fe/f) to be independent of the applied strain. We have in recent publications demonstrated that this stipulation is satisfied within the framework of the statistical theory. However, since this theory is only valid up to moderate strains (∼30%), the question then arises as to howfe/fbehaves at large deformations. In this paper we have examined this problem in the context of phenomenological theories of finite elasticity. It is shown that only for neo‐Hookean strain energy function, which is equivalent to the statistical‐theory free‐energy function, is the value offe/fa constant. For other strain energy functions, such as the Mooney‐Rivlin and Valanis‐Landel functions,fe/fmust decrease with increasing strain. The implication is that in the elasticity of most real rubbers the intermolecular energies play a more important role than previously realized.

 

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