New Aspects of Polymers Containing Quaternary Ammonium Groups
作者:
A. Carpov,
C. Luca,
S. Drăgn,
I. Petrariu,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1985)
卷期:
Volume 22,
issue 5-7
页码: 907-929
ISSN:0022-233X
年代: 1985
DOI:10.1080/00222338508056644
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
It was established that linear polymers with quaternary ammonium groups are obtained by the reaction of chloromethylated polystyrene (CMPS) with hydroxyalkylic tertiary amines when the amines contain one or two hydroxyl groups, and that crosslinked polymers are obtained with aminoether groups when the amines have three hydroxyl groups, i.e., tris(2-hydroxyethy1)amine. The aminoether units appear by intramolecular rearrangement of quaternary ammonium structural units. Kinetic studies on the synthesis of polymers with quaternary ammonium groups from CMPS, poly(N,N-dimethylamino-ethylmethacrylate), and poly(N,N-dimethylaminopropylacrylamide), were performed. The main factors which influence the kinetics of reactions are steric hindrance of near neighboring groups, hydrophilic effect for hydroxyalkylamines and polymer-solvent interaction.
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