An Assessment of the Assignment of Characteristic N-O Vibrations in AromaticN-Oxides
作者:
D.A. Thornton,
G.M. Watkins,
期刊:
Spectroscopy Letters
(Taylor Available online 1992)
卷期:
Volume 25,
issue 7
页码: 1023-1036
ISSN:0038-7010
年代: 1992
DOI:10.1080/00387019208018212
出版商: Taylor & Francis Group
关键词: aromaticN-oxides;infrared;vibrational assignments
数据来源: Taylor
摘要:
The use of “characteristic” N-O group frequencies, in characterising metal complexes with aromaticN-oxides is widespread. The most popular assignments of the N-O in-plane and out-of-plane bends ofN-oxides are shown to be in error, while the validity of transferring the N-O assignments of pyridineN-oxide to larger aromaticN-oxide systems is cautioned.
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