Enhanced thermodynamic stability of tetragonal-phase field in epitaxialPb(Zr,Ti)O3thin films under a two-dimensional compressive stress
作者:
S. Hoon Oh,
Hyun M. Jang,
期刊:
Applied Physics Letters
(AIP Available online 1998)
卷期:
Volume 72,
issue 12
页码: 1457-1459
ISSN:0003-6951
年代: 1998
DOI:10.1063/1.120609
出版商: AIP
数据来源: AIP
摘要:
A two-dimensional thermodynamic model was developed to account for the observed difficulty in the fabrication of epitaxialPb(Zr,Ti)O3(PZT) thin films in which tetragonal and rhombohedral phases coexist. The thermodynamic formalism based on the Landau–Devonshire’s phenomenological theory predicts the enhanced thermodynamic stability of the tetragonal-phase field under a two-dimensional compressive stress. We have experimentally proved this prediction by fabricating an epitaxially oriented tetragonal PZT thin film on MgO substrate with the target composition corresponding to the bulk morphotropic phase boundary (MPB). ©1998 American Institute of Physics.
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