Chromatographic Retention of Ni(II), Co(II) and Cu(II) as Diethyldithio-carbamate Complexes in Presence of Surfactant/n-Propanol/Water Systems: Determination of Micellar Binding Constants
作者:
M.P. San Andrés,
S. Vera,
期刊:
Journal of Liquid Chromatography & Related Technologies
(Taylor Available online 1996)
卷期:
Volume 19,
issue 5
页码: 799-813
ISSN:1082-6076
年代: 1996
DOI:10.1080/10826079608005538
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
This paper presents the values of the micellar binding constants of Ni(II), Co(II) and Cu(II) as complexes with sodium diethyldithiocarbamate, DDTC, in presence of hexadecyltrimethylammonium bromide, CTAB, and sodium dodecylsulphate, SDS, with larger amounts of n-Propanol as organic modifier, by High Performance Liquid Chromatography. Binding constants have been obtained from two equations: a) Arunyanart's treatment, very used for organic compounds but that is not take into account the influence of modifier and b) a multiple regression analysis that permits to consider the high quantities of n-Propanol.
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