Permanganate-Pyruvic Acid Initiated Polymerization of Methacrylamide
作者:
U.D. N. Bajpai,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1981)
卷期:
Volume 16,
issue 3
页码: 629-636
ISSN:0022-233X
年代: 1981
DOI:10.1080/00222338108056810
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A combined system of potassium permanganate and pyruvic acid was found to initiate radical polymerization of vinyl monomers, especially acrylamides. From kinetic investigations of the polymerization of methacrylamide, it was found that this initiator induced a radical polymerization which proceeded with an overall activation energy of 15.7 kcal/mol. The rate is given by
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