X‐Ray K absorption edge studies of cobalt in complexes with nitrogen based aromatic ligands
作者:
A. Kumar,
A. N. Nigam,
B. D. Srivastava,
期刊:
X‐Ray Spectrometry
(WILEY Available online 1981)
卷期:
Volume 10,
issue 1
页码: 25-27
ISSN:0049-8246
年代: 1981
DOI:10.1002/xrs.1300100107
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractThe X‐ray K absorption edges of cobalt in some complexes with nitrogen based ligands [α‐Co(py)2Cl2, Co(py)2Br2, Co(bipy)Br2and Co(phen)Br2] have been recorded using a 40 cm bent crystal spectrogrph. The absorption edge shift and edge width have been discussed in terms of effective nuclear charge, molecular symmetry and the nature of the ligand. The radii of the first coordination sphere have been calculated using Levy's method and a correlation sugge
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