THE RECRYSTALLIZATION OF CALCIUM SOAPS IN MINERAL OILS
作者:
Wilfred Gallay,
Ira E. Puddington,
期刊:
Canadian Journal of Research
(NRC Available online 1944)
卷期:
Volume 22b,
issue 6
页码: 173-181
ISSN:1923-4287
年代: 1944
DOI:10.1139/cjr44b-021
出版商: NRC Research Press
数据来源: NRC
摘要:
The effect of various factors on the stability and physical properties of suspensions of recrystallized calcium stearate is shown. Non-polar oils form lyophobic systems that are unstable. Polar oils yield suspensions that are stable and lyophilic in character with little or no rigidity.The effect of small quantities of water is very marked. As a result of agglomeration, a structure is developed, and the system shows a strong stream double refraction. Lower alcohols have a similar effect. Fatty acid brings about agglomeration also but increasing quantities produce a solvent effect.Calcium oleate behaves similarly to calcium stearate, but the linoleate shows less stability.
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