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THE RECRYSTALLIZATION OF CALCIUM SOAPS IN MINERAL OILS

 

作者: Wilfred Gallay,   Ira E. Puddington,  

 

期刊: Canadian Journal of Research  (NRC Available online 1944)
卷期: Volume 22b, issue 6  

页码: 173-181

 

ISSN:1923-4287

 

年代: 1944

 

DOI:10.1139/cjr44b-021

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The effect of various factors on the stability and physical properties of suspensions of recrystallized calcium stearate is shown. Non-polar oils form lyophobic systems that are unstable. Polar oils yield suspensions that are stable and lyophilic in character with little or no rigidity.The effect of small quantities of water is very marked. As a result of agglomeration, a structure is developed, and the system shows a strong stream double refraction. Lower alcohols have a similar effect. Fatty acid brings about agglomeration also but increasing quantities produce a solvent effect.Calcium oleate behaves similarly to calcium stearate, but the linoleate shows less stability.

 

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