Spectra of the 1:1 and 3:1 solid complexes of coronene-TCNQ
作者:
Kim Doan Truong,
André D. Bandrauk,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1977)
卷期:
Volume 55,
issue 21
页码: 3712-3716
ISSN:0008-4042
年代: 1977
DOI:10.1139/v77-521
出版商: NRC Research Press
数据来源: NRC
摘要:
Two new solid TCNQ complexes have been isolated, coronene–TCNQ 1:1 and 3:1. The infrared and electronic absorption spectra are presented for the two different stoichiometries. From these spectra we infer that the complexes are covalent in the ground state with a charge transfer band appearing at 730 nm. The out of plane vibrations of the individual molecules are noticeably perturbed upon complexation.
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