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Stereoselective Synthesis of Ferrocenylamino Acids

 

作者: Maciej Adamczyk,   RajarathnamE. Reddy,   SushilD. Rege,  

 

期刊: Synthetic Communications  （Taylor Available online 2000）
卷期: Volume 30, issue 8  

页码: 1389-1400

 

ISSN:0039-7911

 

年代: 2000

 

DOI:10.1080/00397910008087166

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Enantiopure ferrocenyl-β, and bis-β-amino acids [(R)-(+)-1 and (R, R)-(+)-2] were prepared from (S)-(+)-sulfinimine (3) and (S, S)-(+)-bis-sulfinimine (4) respectively. The desired sulfinimines [(S)-(+)-3 and (S, S)-(+)-4] were prepared from (S)-Andersen reagent (5) and ferrocenecarboxaldehyde (6) and 1, 1 -ferrocenedicarboxaldehyde (7).

 

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