Kinetics of the catalytic hydrogenation of 2‐Ethyl‐2‐Hexenal
作者:
Dermot J. Collins,
David E. Grimes,
Burtron H. Davis,
期刊:
The Canadian Journal of Chemical Engineering
(WILEY Available online 1983)
卷期:
Volume 61,
issue 1
页码: 36-39
ISSN:0008-4034
年代: 1983
DOI:10.1002/cjce.5450610105
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
Abstract2‐Ethyl‐2‐hexenal was hydrogenated over Raney Nickel and nickel boride in a batch slurry reactor. Using Raney Nickel, the reaction went to completion, and the formation of both 2‐ethylhexanal and 2‐ethylhexanol followed zero order kinetics.Using nickel boride, the reaction ceased at the saturated aldehyde, with saturation of the double bond a zero order reaction. Unsaturated alcohol was not detected in any of the reaction
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