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Transient and steady rheological behavior of the thermotropic liquid crystal copolymer 73/27 HBA/HNA

 

作者: F. Cocchini,   M. R. Nobile,   D. Acierno,  

 

期刊: Journal of Rheology  (AIP Available online 1991)
卷期: Volume 35, issue 6  

页码: 1171-1189

 

ISSN:0148-6055

 

年代: 1991

 

DOI:10.1122/1.550170

 

出版商: The Society of Rheology

 

关键词: Thermotropic polymers;Liquid crystals;Thermotropic steady‐state PLC data;Transient PLC data;COPOLYMERS;THERMOTROPIC CRYSTALS;RHEOLOGY;TRANSIENTS;POLYMERIZATION;STRESSES;VISCOSITY;HYDROXY ACIDS;BENZOIC ACID;SHEAR

 

数据来源: AIP

 

摘要:

Transient and steady rheological measurements of shear and normal stresses are reported for a liquid crystal copolymer of 73 hydroxybenzoic acid/27 hydroxynaphthoic acid. Dynamic time sweeps indicate a sensitiveness of the rheological parameters to thermal history, probably related to polymerization phenomena. In the shear rate range 0.1–1 s−1atT=310 °C the normalized stress overshoots vs strain curves nearly superpose. The steady values of the viscosity seem to follow the three region scheme of Onogi and Asada. The steady values of the first normal stress difference are positive in all the shear rate range analyzed. Constant stress measurements are also reported to prove that the low shear rate data are not significantly affected by the polymerization phenomena. Moreover, the constant stress data show that a true yield stress cannot be detected in the LCP studied.

 

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