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Tensile Strength of Plastics: Effects of Flaws and Chain Relaxation

 

作者: F. Bueche,  

 

期刊: Journal of Applied Physics  (AIP Available online 1958)
卷期: Volume 29, issue 8  

页码: 1231-1234

 

ISSN:0021-8979

 

年代: 1958

 

DOI:10.1063/1.1723408

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A theory for the tensile strength of amorphous plastics is presented. It extends a previous theory so as to include the effects of imperfections and chain relaxations. The result obtained shows that the time taken for a plastic to break,tc, under constant stress,F, is given byF=−Bln(tc)+C,whereBandCare molecular constants. The experimental values found for these constants are shown to be consistent with their molecular interpretation. This extended theory shows that the effect of chain relaxations is the major time dependent factor as far as strength is concerned.

 

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