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A Recurrent Novel Motif For 3-Dimensional Magnetic Exchange Interactions in Chain Structures Containing Endo-Bidentate α-Di-Imine Ligands: π-π Overlap Interactions

 

作者: W.M. Reiff,   C.C. Torardi,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 1995）
卷期: Volume 274, issue 1  

页码: 187-192

 

ISSN:1058-725X

 

年代: 1995

 

DOI:10.1080/10587259508031880

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Weakly associated five coordinate monomers based on high-spin trivalent iron α-di-imine complexes are found to exhibit surprisingly strong magnetic exchange interactions that lead to easily discerned 1-and 3-dimensional antiferromagnetic exchange and ordering effects respectively.

 

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