Kinetics of cumene synthesis over ferrisilicate of MFI structure
作者:
P. A Parikh,
N. Subrahmanyam,
Y. S. Bhat,
A. B. Halgerp,
期刊:
The Canadian Journal of Chemical Engineering
(WILEY Available online 1993)
卷期:
Volume 71,
issue 5
页码: 756-760
ISSN:0008-4034
年代: 1993
DOI:10.1002/cjce.5450710513
出版商: Wiley Subscription Services, Inc., A Wiley Company
关键词: alkylation;ferrisilicate of MFI structure;cumene;kinetics;zeolites.
数据来源: WILEY
摘要:
AbstractBenzene isopropylation over medium port ferrisilicate to obtain cumene has been studied. Effects of reaction conditions on cumene selectivity are discussed. Based on the reaction network, various models were derived and fitted to kinetic data. A simple stoichiometric model represented the kinetic data significantly better than other models. Estimated activation energy values indicated that benzene alkylation is faster than cumene isomerisation to n‐propylbenzen
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