Radiation-Induced Emulsion Copolymerization of Tetrafluoroethylene with Propylene. II. Formulas and Conditions
作者:
Nobutake Suzuki,
Osamu Matsuda,
Jiro Okamoto,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1974)
卷期:
Volume 8,
issue 4
页码: 793-804
ISSN:0022-233X
年代: 1974
DOI:10.1080/00222337408066398
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Formulas and reaction conditions for the radiation-induced emulsion copolymerization of tetrafluoroethylene with propylene were studied at room temperature in the presence of gaseous monomers containing 50 mole % tetrafluoroethylene content. Stable latex was obtained by the use of ammonium perfluorooctanoate emulsifier. The resulting copolymer was a rubberlike material. A percentage of emulsifier greater than 1 wt% to water was suitable in this emulsion copolymerization. The conversion and the molecular weight were independent of the stirring speed above 400 rpm and decreased with a rise in temperature. An induction period was observed in the presence of oxygen. There was no effect of water purity on the emulsion copolymerization. When the stainless-steel reaction vessel was cleaned with a dilute acidic aqueous solution, the conversion was almost the same as that for a Pyrex reaction vessel.
点击下载:
PDF (428KB)
返 回