Enhanced chemiluminescence in the oxidation of luminol and an isoluminol cortisol conjugate by hydrogen peroxide in reversed micelles
作者:
D. I. Metelitza,
A. N. Eryomin,
V. A. Shibaev,
期刊:
Journal of Bioluminescence and Chemiluminescence
(WILEY Available online 1992)
卷期:
Volume 7,
issue 1
页码: 21-26
ISSN:0884-3996
年代: 1992
DOI:10.1002/bio.1170070104
出版商: John Wiley&Sons, Ltd.
关键词: Enhanced chemiluminescence;luminol;isoluminol conjugate;reversed micelles;cetyltrimethylammonium bromide
数据来源: WILEY
摘要:
AbstractThe chemiluminescent oxidation of luminol and an isoluminol cortisol conjugate (ABICOR) by hydrogen peroxide has been studied in cetyltrimethylammonium bromide (CTAB) reversed micelles in octane‐chloroform (1 : 1). The maximum chemiluminescence intensity of both compounds is dependent on the initial concentrations of the H2O2and substrates, the pH value of the micelle polar phase and the H2O/CTAB ratio. The optimum pH ranged from 8.5 to 9.5. Under comparable conditions, the chemiluminescence intensity for luminol was 15‐fold higher than for the ABI‐COR conjugate. A mechanism of oxidation of the substrates in reversed micelles is proposed and the possible mechanisms of inhibition by the substrate and oxidant is disc
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