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Influence of the Bulk and Donor-Acceptor Properties of Solvent on Ligand Field Spectra

 

作者: Zbigniew Staszak,   Adam Bartecki,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1989）
卷期: Volume 22, issue 9  

页码: 1193-1201

 

ISSN:0038-7010

 

年代: 1989

 

DOI:10.1080/00387018908054016

 

出版商: Taylor & Francis Group

 

关键词: electronic absorption spectra;solvent effect;bulk properties;donor-acceptor properties;chromium (III) complexes

 

数据来源: Taylor

 

摘要:

The influence of solvents on the electronic absorption spectra of chromium (III) complexes was investigated. The dependence of the crystal field parameter Dq on dielectric constant as well as Gutmann donor number DN of solvent was found and described. By using the proposed model, unknown in the literature donor numbers for a few alcohols were estimated.

 

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