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Peculiarities of The Thermal Expansion of ICl Mono- and Hetero-Graphite Intercalation Compounds under Order-Disorder Phase Transitions

 

作者: SergueyG. Ionov,   ValdimirA. Kulbachinskii,   ElenaN. Pavlova,   ValeriyP. Popov,   AlexeyG. Sokolov,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 1998）
卷期: Volume 310, issue 1  

页码: 93-98

 

ISSN:1058-725X

 

年代: 1998

 

DOI:10.1080/10587259808045320

 

出版商: Taylor & Francis Group

 

关键词: phase transition;graphite intercalation compounds

 

数据来源: Taylor

 

摘要:

The temperature dependence of the thermal expansion coefficient α in highly oriented pyrolytic graphite (HOPG), first stage graphite intercalation compound (GIC) C8.1ICl1.1, second stage GIC C16.3ICl1.1, hetero-intercalated compounds C12FeCl3(ICl)0.75and C10CuCl2(ICl)0.6in the main crystallographic directions in the temperature range 40<T<350 K has been investigated. It was shown that the Debye temperatures in plane and in the perpendicular direction are different in ICl graphite intercalation compounds.

 

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