Preparation of narrow pores carbon suitable for hydrogen sulfide adsorption
作者:
S. Tanada,
T. Kita,
K. Boki,
Y. Kozaki,
期刊:
Journal of Environmental Science and Health . Part A: Environmental Science and Engineering
(Taylor Available online 1985)
卷期:
Volume 20,
issue 1
页码: 87-96
ISSN:0360-1226
年代: 1985
DOI:10.1080/10934528509375211
出版商: Taylor & Francis Group
关键词: Preparation;N‐Containing activated carbon;Micropores;Adsorption;Hydrogen sulfide
数据来源: Taylor
摘要:
Microporous N‐containing activated carbon (N‐CAC) suitable for hydrogen sulfide adsorption was prepared by impregnating raw activated carbon with a 25% methylol melamine urea solution and then heating it at different temperatures from 100 to 1000°C. The structures of raw activated carbon and N‐CAC Ho. 8 carbonized at the most suitable temperature 850°C have been discussed based on applying the Dubinin‐Radushkevich equation to adsorption isotherm of hydrogen sulfide. The 12.2% increase in micropore volume of N‐CAC No. 8 result from the numerical increase of micropores rather than radial expansion of micropores. The relation of q and AS could be consistently explained by the interaction of hydrogen sulfide with micropores of adsorbents.
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