首页   按字顺浏览 期刊浏览 卷期浏览 Retention Time in Nonlinear Gas-Liquid Chromatography. Influence of the Sample Size. Pa...
Retention Time in Nonlinear Gas-Liquid Chromatography. Influence of the Sample Size. Part II. Case of a Nonlinear Isotherm

 

作者: Jean-Yves Lenoir,   Alexandre Rojey,  

 

期刊: Separation Science  (Taylor Available online 1972)
卷期: Volume 7, issue 1  

页码: 13-24

 

ISSN:0037-2366

 

年代: 1972

 

DOI:10.1080/00372367208058968

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The effect of the sample size on the retention time is studied both experimentally and theoretically. It has already been shown that the deviation of the retention time from its value at infinite dilution is a consequence of a nonlinearity in the basic transfer relations. The previous approach is extended to systems for which the equilibrium isotherm is no longer linear. The relative deviation is either positive or negative according to the curvature of the isotherm. A good agreement between predicted and experimental values is obtained.

 

点击下载:  PDF (349KB)



返 回