Retention Time in Nonlinear Gas-Liquid Chromatography. Influence of the Sample Size. Part II. Case of a Nonlinear Isotherm
作者:
Jean-Yves Lenoir,
Alexandre Rojey,
期刊:
Separation Science
(Taylor Available online 1972)
卷期:
Volume 7,
issue 1
页码: 13-24
ISSN:0037-2366
年代: 1972
DOI:10.1080/00372367208058968
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The effect of the sample size on the retention time is studied both experimentally and theoretically. It has already been shown that the deviation of the retention time from its value at infinite dilution is a consequence of a nonlinearity in the basic transfer relations. The previous approach is extended to systems for which the equilibrium isotherm is no longer linear. The relative deviation is either positive or negative according to the curvature of the isotherm. A good agreement between predicted and experimental values is obtained.
点击下载:
PDF (349KB)
返 回