Rotational line intensities in zero kinetic energy photoelectron spectroscopy (ZEKE-PES)
作者:
Frédéric Merkt,
TimothyP. Softley,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1993)
卷期:
Volume 12,
issue 2
页码: 205-239
ISSN:0144-235X
年代: 1993
DOI:10.1080/01442359309353282
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Recent advances in the understanding of the factors which determine line intensities in zero kinetic energy photoelectron spectroscopy (ZEKE-PES) are reviewed. The relative importance of direct ionization and autoionization is assessed. Explicit consideration of the channel interactions which take place in the vicinity of molecular ionization thresholds leads to a general discussion of rotational line intensities in ZEKE-PES. A series of limiting cases is proposed to assist in the interpretation of experimental results. Finally a new dynamical interpretation of ZEKE experiments based on the trapping of the ZEKE electrons in non-penetrating high-lRydberg orbitals by weak electric fields appears to give a satisfactory explanation of most experimental results obtained to date.
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